Water Treatment for Central Heating Systems
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Few car owners would expect their vehicle to perform reliably for years without ever checking levels of oil and water or servicing the vehicle. Yet many householders do just this when it comes to the "engine" of their heating system, their central heating boiler, or the other parts of the system that provide vital warmth and hot water throughout the year.
Water treatment (WT) is one of the measures necessary to ensure good heating system performance. An efficient boiler, effective controls, fully-functioning radiators and correct system protection and maintenance - achieved by the right water treatment regime - all help to keep your energy bills lower.
That is why Building Regulations , British Standards  and most boiler manufacturers' installation instructions now give recommendations on the use of WT chemicals and other devices such as system filters. These help to ensure that both the boiler and the heating system perform reliably and efficiently throughout their expected lifetime.
The following is a brief guide to the different types of WT chemicals and devices and what they do. More detailed information is given in the documents listed under References, or in the instructions for the WT product concerned.
The WT manufacturer's dosage specifications and user instructions must be followed and the correct procedures must be used when carrying out the operations described below. "Conventional" cleaning and flushing and use of inhibitors as described below should ideally be carried out by a competent person. Power-flushing should only be carried out by a competent person.
Water treatment for central heating systems covers three main areas - cleaning, protection and maintenance.
The boiler manufacturer's instructions (and warranty) require that cleaning and flushing if the system is carried out prior to boiler installation. This is also a requirement in Building Regulations (see box below).
A newly-installed central heating system may contain residual debris such as metal particles, solder residue etc., while an older system which has not been correctly protected with inhibitors (see below) may contain corrosion deposits in the form of accumulated "sludge" in pipes, radiators etc. The illustration below shows accumulated sludge being removed from a radiator.
Accumulation of sludge may be an indication of electrolytic corrosion in the heating system. This can occur because of contact between different metals used in heating system components and may be accompanied by the accumulation of flammable gas within radiators - which may be mistaken as air accumulation in very severe cases.
If a new boiler is to be installed then it is obviously important to ensure that the heating system (pipes and radiators) to which it is being connected, whether old or new, is as clean as possible. Any internal debris or deposits could ultimately be washed into the boiler and its heat exchanger, affecting performance and possibly causing a major breakdown. Accumulated sludge in radiators can also affect the circulation of water in the primary circuit, affecting heat output and leading to a reduction in efficiency of the system as a whole.
A common symptom of sludge accumulation is that radiators are cold at the bottom but hot at the top - due to reduced water flow. The illustration below shows a "thermal image" of a radiator with reduced water flow due to blockage (cooler region in purple).
Treatment chemicals may range from mild detergent-based cleaners suitable for removing debris after the installation of new systems or modification of existing systems, through to more aggressive cleaners designed to remove accumulated deposits in existing systems which may not have been treated for some time.
BS 7593 specifies a number of cleaning methods which will meet the requirements of Building Regulations. Detailed guidance is given in the standard, but in outline these are as follows -
1. A conventional clean and flush - using gravity to empty and re-fill the system and adding WT chemicals as required. Cleaning and flushing are accomplished by repeated filling and draining of the system, after using appropriate WT chemicals to suspend, disperse and remove accumulated material. This is then followed by a "flush" with clean water, before any inhibitors are added to protect the system (see below).
2. Mains pressure clean and flush - This involves the connection of a mains pressure hose to an appropriate point on the heating system and another hose from the system's drain valve to a suitable foul drain. After using WT chemicals to suspend, disperse and remove accumulated material, individual radiators on the heating circuit are flushed using mains pressure water by opening/closing their isolation valves in turn, before flushing the whole system with all valves open. The system is then refilled, using inhibitor (see below) as required and returning all radiator valves to their previous settings.
A second possibility is to drain and remove individual radiators and clean them (preferably having taken them outside) by flushing with mains pressure water. This can be a time-consuming process and may result in some disturbance and mess. This method may not clean any accumulated deposits in the system pipework and further flushing may be necessary to achieve this. Use of inhibitors will again be required once the system has been re-assembled and refilled.
3. "Power-flushing" - which uses a specially-designed pumping system to rapidly circulate water and treatment chemicals around the heating circuit.
If a new boiler is being installed, power-flushing should be carried out prior to installation, or with the boiler isolated from the system. If an existing system is being maintained then isolation of the boiler is normally required to avoid blockage by deposits dislodged during cleaning.
The manufacturer of the power-flushing system will provide detailed instructions and may also specify the treatment procedures and chemicals to be used. These instructions must be followed.
Note: power-flushing may not be suitable for some systems - e.g. gravity systems, single pipe systems and some micro-bore systems. More detailed guidance is available elsewhere - e.g. from power-flushing equipment manufacturers.
With all cleaning methods it is important to ensure that cleaning agents are completely removed from the heating system as they may nullify the effect of the inhibitor. Additionally, if cleaners remain present, having mobilized the system debris the resultant mixture can lead to premature failure of system components (e.g. pumps) and can also lead to flammable gases e.g. hydrogen being formed within the central heating circuit if corrosion re-occurs due to the reduced effectiveness of the inhibitor.
Once the system has been cleaned, it is important to ensure that the corrosion processes which caused internal deposits to form and accumulate do not re-occur. Left untreated, internal corrosion can again lead to sludge formation, which will cause reduction of water flow and reduced system efficiency. The system water content must therefore be treated with a chemical "inhibitor" to minimise corrosion of the various metals within the system.
It is important to ensure that the inhibitor used is compatible with the metals and other materials present in the heating system - as specified in accompanying instructions. It is also important to ensure that the product is Buildcert approved (or equivalent) .
WT chemicals such as inhibitors for "open vented" heating systems are usually added to the system via the header tank in the loft. For unvented/sealed systems, WT products are often sold in containers which attach to "mastic guns", as used for bathroom filler/sealant products - although other product types are available. These allow the WT product to be introduced via an appropriate connection to the sealed heating system - following the instructions provided by the manufacturer.
Lack of water treatment, particularly in hard water areas, can also lead to formation of limescale in the boiler's heat exchanger, which can lead to reduced efficiency and boiler noise. Most inhibitors will contain ingredients to prevent limescale formation.
Once a system is cleaned and protected it is important to ensure that the concentration of inhibitor is checked and maintained so that it continues its preventative action. Inhibitors are designed to have an extended lifetime in the heating system; however most WT manufacturers recommend checking concentration at annual boiler service intervals and will offer a simple test kit to do this.
A major cause of corrosion is oxygen introduced when the system is "topped up" with fresh water. Water may occasionally be drained from the heating system for maintenance, or to allow removal of radiators whilst decorating. If the system is then re-filled without adding further inhibitor the concentration will be reduced - possibly to zero if the system was completely drained. It is therefore important to ensure that inhibitor is always "topped up" after system drainage.
Note: an unvented system should not require frequent "topping up" due to gradual loss of system pressure. If frequent topping up is required then the system is leaking and this should be rectified so that associated corrosion does not take place.
It is also recommended that whenever WT products are used, a label (normally provided with the product) is attached to the system to act as a record of which product was used, in what concentration - and when. The Benchmark Commissioning Checklist, completion of which is required when a new boiler is installed, should also be used to record the inhibitor type and concentration used on commissioning.
Note: current BEAMA Water Treatment  guidance suggests that mixing of different WT manufacturers' products is not advisable. If the make of the inhibitor is not known then it is better to drain the system and re-fill, adding new inhibitor to the manufacturer's recommended concentration.
SYSTEM FILTRATION DEVICES
A number of different filtration devices are now on the market, in addition to the chemical water treatments described above. These can incorporate magnetic or "cyclone" arrangements (or a combination of these) to remove fine particles suspended in the water circulating around the system. These devices help to maintain system cleanliness and provide an additional level of protection.
WATER SOFTENERS AND CENTRAL HEATING BOILERS
Where a water softener is present in the dwelling, ensure that the heating system primary circuit is filled with mains water via the general bypass valve as required in BS 14173.
Note: A water softener must comply with BS 14173 (this states that there must be ‘a general bypass valve which enables the softening unit to be isolated from the mains, while maintaining water supply to the end user'. For installation requirements, refer to WRAS Information and guidance Note No 9-07-01 "Information for the installation of ion exchange water softeners for systems supplying water for domestic purposes".
Refer to the boiler manufacturer's instructions for any additional advice on softened water.
 Building Regulations, Approved Document L - Domestic Heating Compliance Guide http://www.planningportal.gov.uk/uploads/br/domestic_building_services_compliance_guide.pdf
 British Standards - available from BSI
BS 7593 - Code of practice for treatment of water in domestic central heating systems
BS 6798 - Specification for selection, installation, inspection, commissioning, servicing and maintenance of gas-fired boilers of rated input not exceeding 70 kW net
BS EN 14743 - Water conditioning equipment inside buildings. Softeners. Requirements for performance, safety and testing
 BuildCert Chemical Inhibitor Approval Scheme (CIAS) http://www.beama.org.uk/download.cfm/docid/83DC22C1-2FCB-4D80-A663E9BD1277BDA5
 BEAMA Code of Practice for Chemical Cleaning and Inhibiting of Domestic Hot Water Central Heating Systems. http://www.beama.org.uk/download.cfm/docid/E2280148-AB02-4E16-B7E1710BE610870A
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